Non‐innocent Behaviour of Dithiocarboxylate Ligands Based on N‐Heterocyclic Carbenes | Zendy

Naeem Saira | Zendy; Thompson Amber L. | Zendy; Delaude Lionel | Zendy; WiltonEly James D. E. T. | Zendy

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Non‐innocent Behaviour of Dithiocarboxylate Ligands Based on N‐Heterocyclic Carbenes

Author(s) -

Naeem Saira,

Thompson Amber L.,

Delaude Lionel,

WiltonEly James D. E. T.

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001235

Subject(s) - steric effects , denticity , chemistry , ligand (biochemistry) , chelation , stereochemistry , combinatorial chemistry , computer science , organic chemistry , crystal structure , biochemistry , receptor

Not so innocent : Sterically tuneable dithiocarboxylate ligands derived from N‐heterocyclic carbenes act as excellent bidentate chelates for ruthenium(II) σ‐alkenyl complexes. However, the most sterically demanding member of the ligand family causes a fascinating and unexpected rearrangement to occur (see figure; ICy=1,3‐dicylohexylimidazolium, IDip=1,3‐bis(2,6‐diisopropylphenyl)imidazolium).

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