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U III ‐Induced Reductive Co‐Coupling of NO and CO to Form U IV Cyanate and Oxo Derivates
Author(s) -
Frey Alistair S. P.,
Cloke F. Geoffrey N.,
Coles Martyn P.,
Hitchcock Peter B.
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001231
Subject(s) - bridging (networking) , cyanate , content (measure theory) , chemistry , computer science , physics , mathematics , polymer chemistry , computer network , mathematical analysis
CO and NO give NCO and O! Sequential treatment of [U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)] with CO followed by NO (or vice versa) affords a mixture of the bridging cyanate complex [{U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)} 2 (μ‐OCN) 2 ] and the bridging oxo complex [{U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)} 2 (μ‐O)], both of which have been structurally characterised (see scheme).