U III ‐Induced Reductive Co‐Coupling of NO and CO to Form U IV  Cyanate and Oxo Derivates | Zendy

Frey Alistair S. P. | Zendy; Cloke F. Geoffrey N. | Zendy; Coles Martyn P. | Zendy; Hitchcock Peter B. | Zendy

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U III ‐Induced Reductive Co‐Coupling of NO and CO to Form U IV Cyanate and Oxo Derivates

Author(s) -

Frey Alistair S. P.,

Cloke F. Geoffrey N.,

Coles Martyn P.,

Hitchcock Peter B.

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201001231

Subject(s) - bridging (networking) , cyanate , content (measure theory) , chemistry , computer science , physics , mathematics , polymer chemistry , computer network , mathematical analysis

CO and NO give NCO and O! Sequential treatment of [U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)] with CO followed by NO (or vice versa) affords a mixture of the bridging cyanate complex [{U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)} 2 (μ‐OCN) 2 ] and the bridging oxo complex [{U(η‐C 8 H 6 {Si i Pr 3 ‐1,4} 2 )(η‐Cp*)} 2 (μ‐O)], both of which have been structurally characterised (see scheme).

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