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Polyoxometalate‐Based N‐Heterocyclic Carbene (NHC) Complexes for Palladium‐Mediated CC Coupling and Chloroaryl Dehalogenation Catalysis
Author(s) -
Berardi Serena,
Carraro Mauro,
Iglesias Manuel,
Sartorel Andrea,
Scorrano Gianfranco,
Albrecht Martin,
Bonchio Marcella
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201001009
Subject(s) - carbene , palladium , halogenation , polyoxometalate , catalysis , chemistry , combinatorial chemistry , coupling (piping) , medicinal chemistry , organic chemistry , materials science , metallurgy
Better together : A novel hybrid N‐heterocyclic carbene (NHC) palladium complex, integrating a totally inorganic and polyanionic decatungstate unit, has been synthesized following a convergent strategy. The interplay of the Pd binding domains with the inorganic scaffold is instrumental in accessing multi‐turnover catalysis in CC cross‐coupling and aromatic dehalogenation reactions under MW‐assisted protocols (see scheme).