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Two Novel Copper–Undecaniobates Decorated by Copper–Organic Cations [{Cu(H 2 O)L} 2 {CuNb 11 O 35 H 4 }] 5− (L=1,10‐phenanthroline, 2,2′‐bipyridine) Consisting of Plenary and Monolacunary Lindqvist‐Type Isopolyniobate Fragments
Author(s) -
Niu JingYang,
Chen Guo,
Zhao JunWei,
Ma PengTao,
Li SuZhi,
Wang JingPing,
Li MingXue,
Bai Yan,
Ji BianSheng
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201000824
Subject(s) - copper , chemistry , crystallography , materials science , inorganic chemistry , organic chemistry
Keep it in the family : Two novel copper–undecaniobates [{Cu(H 2 O)L} 2 {CuNb 11 O 35 H 4 }] 5− (L=1,10‐phenanthroline or 2,2′‐bipyridine, an example is shown here) have been successfully synthesized by the diffusion strategy and, as far as we know, represent the first examples of copper–undecaniobates in the polyoxoniobate family.