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Hexazirconium‐ and Hexahafnium‐Containing Tungstoarsenates(III) and Their Oxidation Catalysis Properties
Author(s) -
AlKadamany Ghada,
Mal Sib Sankar,
Milev Borislav,
Donoeva Baira G.,
Maksimovskaya Raisa I.,
Kholdeeva Oxana A.,
Kortz Ulrich
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201000786
Subject(s) - solid state , information retrieval , catalysis , computer science , chemistry , combinatorial chemistry , world wide web , organic chemistry
Six of the best! Two Zr 6 ‐ and Hf 6 ‐containing tungstoarsenates(III) [M 6 O 4 (OH) 4 (H 2 O) 2 (CH 3 COO) 5 (AsW 9 O 33 ) 2 ] 11− (M=Zr, Hf) have been synthesized and structurally characterized in solution and in the solid state, and both species are highly active in H 2 O 2 ‐based selective oxidations.