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Dendronizing and Metalating trans‐ 2 C 60 Tetraaryl Porphyrins—A Versatile Approach Toward Water‐Soluble Donor–Acceptor Conjugates
Author(s) -
Ruppert Michaela,
Spänig Fabian,
Wielopolski Mateusz,
Jäger Christof M.,
Bauer Walter,
Clark Timothy,
Hirsch Andreas,
Guldi Dirk M.
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201000760
Subject(s) - porphyrin , dendrimer , acceptor , chemistry , photochemistry , charge (physics) , electron acceptor , conjugate , electron donor , recombination , metal , catalysis , polymer chemistry , organic chemistry , physics , mathematics , quantum mechanics , condensed matter physics , biochemistry , gene , mathematical analysis
We have realized for the first time a series of truly water‐soluble and tightly coupled porphyrin/C 60 electron‐donor–acceptor conjugates in which the charge separation and charge recombination dynamics are controlled by modifying the nature of the dendrimer and/or the choice of the central metal atom.