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Designing Surface‐Confined Coordination Oligomers
Author(s) -
Altman Marc,
Rachamim Meital,
Ichiki Takahiko,
Iron Mark A.,
Evmenenko Guennadi,
Dutta Pulak,
van der Boom Milko E.
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201000690
Subject(s) - chromophore , covalent bond , coordination complex , computer science , nanotechnology , chemistry , materials science , polymer science , organic chemistry , metal
Designer materials : HOMO–LUMO engineering of coordination‐based oligomers covalently bound to silicon or glass has been achieved by the use of a partially fluorinated chromophore (see graphic). The experimental and computationally derived physical chemical properties of these assemblies are compared to their non‐fluorinated analogues.