Through‐Space Ligand Interactions in Enantiomeric Dinuclear Ru Complexes | Zendy

Planas Nora | Zendy; Christian Gemma J. | Zendy; MasMarzá Elena | Zendy; Sala Xavier | Zendy; Fontrodona Xavier | Zendy; Maseras Feliu | Zendy; Llobet Antoni | Zendy

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Through‐Space Ligand Interactions in Enantiomeric Dinuclear Ru Complexes

Author(s) -

Planas Nora,

Christian Gemma J.,

MasMarzá Elena,

Sala Xavier,

Fontrodona Xavier,

Maseras Feliu,

Llobet Antoni

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.201000585

Subject(s) - zonal and meridional , denticity , ligand (biochemistry) , enantiomer , stereochemistry , chemistry , crystallography , computer science , physics , crystal structure , biochemistry , receptor , atmospheric sciences

Molecular twisting : A family of dinuclear Ru complexes of general formula [{Ru(T)(L)} 2 (μ‐bpp)] ( n +1)+ (T=tridentate meridional ligand; bpp=tetradentate bridging ligand and L=monodentate ligand, n =1 or 2) have been prepared and thoroughly characterized. In solution these complexes display a global dynamic behavior in which the monodentate ligands undergo a synchronized twisting motion.

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