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Synthesis of Polycyclic Compounds by a Cascade Cycloisomerisation/Diels–Alder Reaction
Author(s) -
Barluenga José,
Calleja Jonás,
Mendoza Abraham,
Rodríguez Félix,
Fañanás Francisco J.
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201000515
Subject(s) - cascade , diels–alder reaction , cycloaddition , chemistry , scheme (mathematics) , computer science , combinatorial chemistry , computational chemistry , organic chemistry , mathematics , catalysis , mathematical analysis , chromatography
Running rings around gold : A new cascade reaction catalysed by AuCl 3 that is based upon an initial cycloisomerisation reaction of enynol or enynamine derivatives, which form 1,3‐butadiene derivatives, followed by a Diels–Alder cycloaddition reaction to give fused or spirocyclic compounds is reported (see scheme).