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A Three‐Component Modular Strategy to Extend and Link Coordination Complexes by Using Halogen Bonds to O, S and π Acceptors
Author(s) -
Lapadula Giuseppe,
Judaš Nenad,
Friščić Tomislav,
Jones William
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201000049
Subject(s) - halogen , component (thermodynamics) , modular design , link (geometry) , chemistry , combinatorial chemistry , stereochemistry , computer science , organic chemistry , programming language , physics , computer network , alkyl , thermodynamics
Strategic extension! A modular strategy, involving the recognition and assembly of three molecular components, was used to decorate complexes of Ni II and Co II with halogen bonds of I⋅⋅⋅S and I⋅⋅⋅O type. In addition to this rational implementation of halogen bonding to extend coordination structures, the resulting materials also demonstrate the self‐assembly through I⋅⋅⋅π interactions as a means to form polymers based on coordination and halogen bonds (see graphic).