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Kumada–Corriu Cross‐Couplings with 2‐Pyridyl Grignard Reagents
Author(s) -
Ackermann Lutz,
Potukuchi Harish K.,
Kapdi Anant R.,
Schulzke Carola
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.201000032
Subject(s) - scope (computer science) , reagent , phosphine , content (measure theory) , computer science , chemistry , phosphine oxide , combinatorial chemistry , information retrieval , database , organic chemistry , mathematics , catalysis , programming language , mathematical analysis
SPOs meet the challenge : A palladium complex derived from air‐ and moisture‐stable secondary phosphine oxide (SPO) (1‐Ad) 2 P(O)H enables general cross‐coupling reactions of challenging electron‐deficient 2‐pyridyl Grignard reagents with ample scope (see scheme).