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Inside Cover: Striking AcOH Acceleration in Direct Intramolecular Allylic Amination Reactions (Chem. Eur. J. 42/2009)
Author(s) -
Nahra Fady,
Liron Frédéric,
Prestat Guillaume,
Mealli Carlo,
Messaoudi Abdelatif,
Poli Giovanni
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200990164
Subject(s) - palladium , amination , intramolecular force , allylic rearrangement , chemistry , benzoquinone , solvent , catalysis , cover (algebra) , photochemistry , polymer chemistry , medicinal chemistry , organic chemistry , engineering , mechanical engineering
AcOH as the solvent… enables extraordinarily fast and effective palladium(II)‐catalyzed direct intramolecular allylic aminations by assisting the benzoquinone‐mediated palladium reoxidation and ionization of the intermediate palladium complexes. For details see the Communication by Poli et al. on page 11078 ff.