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Cover Picture: Theoretical Study on the Halogen–Zinc Exchange Reaction by Using Organozincate Compounds (Chem. Eur. J. 23/2009)
Author(s) -
Nakamura Shinji,
Liu ChingYuan,
Muranaka Atsuya,
Uchiyama Masanobu
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200990082
Subject(s) - halogen , zinc , chemistry , cover (algebra) , substrate (aquarium) , computational chemistry , alkyl , density functional theory , inorganic chemistry , stereochemistry , organic chemistry , mechanical engineering , oceanography , engineering , geology
Density functional theory and fragment‐energy analysis have been used to probe the mechanism of the halogen–zinc exchange reaction. In their Full Paper on page 5686 ff. , M. Uchiyama, S. Nakamura et al. discuss three important factors in this reaction: The effect of the halogen species, the effect of the alkyl ligand on zinc, and the effect of the substrate nature.