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Framework Solids Possessing Both Hydrophobic and Hydrophilic Pores Constructed by Face‐Sharing Keplerate‐Type Heterometal–Organic Polyhedra
Author(s) -
Kong XiangJian,
Zhang Han,
Zhao HaiXia,
Ren YanPing,
Long LaSheng,
Zheng Zhiping,
Nichol Gary S.,
Huang RongBin,
Zheng LanSun
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200903430
Subject(s) - isostructural , polyhedron , face (sociological concept) , type (biology) , nanoscopic scale , metal organic framework , computer science , materials science , nanotechnology , crystallography , chemical engineering , chemistry , geology , mathematics , geometry , crystal structure , sociology , engineering , paleontology , social science , adsorption
Interesting MOPs! Two isostructural framework structures built from novel Keplerate‐type 3d–4f heterometal–organic polyhedra (HMOPs), both with hydrophilic and hydrophobic pores of nanoscopic dimensions, have been obtained. The 36‐metal HMOPs display an aesthetically pleasing double‐Archimedean solid structure characterized by a cuboctahedron encapsulating a rhombicuboctahedron (see figure).