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Low‐Temperature Ag/Pd‐Catalyzed Decarboxylative Cross‐Coupling of Aryl Triflates with Aromatic Carboxylate Salts
Author(s) -
Gooßen Lukas J.,
Lange Paul P.,
Rodríguez Nuria,
Linder Christophe
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200903319
Subject(s) - aryl , catalysis , decarboxylation , carboxylate , palladium , chemistry , coupling (piping) , combinatorial chemistry , copper , organic chemistry , medicinal chemistry , polymer chemistry , materials science , metallurgy , alkyl
At 50°C lower than the best known copper catalysts , a catalytic silver(I)/palladium(II) system allows the decarboxylative cross‐coupling of arenecarboxylates with aryl triflates at temperatures as low as 120 °C. Remarkably, polychlorinated and many heterocyclic arenecarboxylates are converted for the first time in high yields. FG=functional group.