Low‐Temperature Ag/Pd‐Catalyzed Decarboxylative Cross‐Coupling of Aryl Triflates with Aromatic Carboxylate Salts | Zendy

Gooßen Lukas J. | Zendy; Lange Paul P. | Zendy; Rodríguez Nuria | Zendy; Linder Christophe | Zendy

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Low‐Temperature Ag/Pd‐Catalyzed Decarboxylative Cross‐Coupling of Aryl Triflates with Aromatic Carboxylate Salts

Author(s) -

Gooßen Lukas J.,

Lange Paul P.,

Rodríguez Nuria,

Linder Christophe

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200903319

Subject(s) - aryl , catalysis , decarboxylation , carboxylate , palladium , chemistry , coupling (piping) , combinatorial chemistry , copper , organic chemistry , medicinal chemistry , polymer chemistry , materials science , metallurgy , alkyl

At 50°C lower than the best known copper catalysts , a catalytic silver(I)/palladium(II) system allows the decarboxylative cross‐coupling of arenecarboxylates with aryl triflates at temperatures as low as 120 °C. Remarkably, polychlorinated and many heterocyclic arenecarboxylates are converted for the first time in high yields. FG=functional group.

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