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Photooxidation of N‐Confused Porphyrin: A Route to N‐Confused Biliverdin Analogues
Author(s) -
Wojaczyński Jacek,
LatosGrażyński Lechosław
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200903182
Subject(s) - biliverdin , porphyrin , clarity , confusion , information retrieval , chemistry , computer science , history , philosophy , psychology , photochemistry , organic chemistry , biochemistry , heme , heme oxygenase , psychoanalysis , enzyme
Clarity through confusion : The photooxidation of an N‐confused porphyrin dianion provides a unique N‐confused biliverdin analogue with two types of coordination surroundings: (NNNO) and (CNOO), as demonstrated by a palladium(II) complex (see figure).