[PdCl 2 (MeCN) 2 ]‐Catalyzed Highly Regio‐ and Stereoselective Allylation of Electron‐Rich Arenes with 2,3‐Allenoates | Zendy

Fang Zhao | Zendy; Fu Chunling | Zendy; Ma Shengming | Zendy

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[PdCl 2 (MeCN) 2 ]‐Catalyzed Highly Regio‐ and Stereoselective Allylation of Electron‐Rich Arenes with 2,3‐Allenoates

Author(s) -

Fang Zhao,

Fu Chunling,

Ma Shengming

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200903012

Subject(s) - anisole , stereoselectivity , chemistry , phenol , dimethylacetamide , palladium , catalysis , organic chemistry , medicinal chemistry , combinatorial chemistry , solvent

Selective allylation : Several electron‐donating arenes such as 1,3,5‐trimethoxybenzene, anisole, and phenol underwent palladium‐catalyzed selective allylation in TFA/dimethylacetamide (DMA) under mild conditions with 2,3‐allenoates (see scheme). The reaction afforded substituted 4,4‐diarylbut‐2( E )‐enoates in moderate yields with high regio‐ and stereoselectivity.

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