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From an Organic‐Functionalized Ge 4 S 6 Cage to a Chalcogenidometallate Organic Coordination Framework with Antiferromagnetic Chain Behavior
Author(s) -
Hassanzadeh Fard Zohreh,
Clérac Rodolphe,
Dehnen Stefanie
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200902921
Subject(s) - antiferromagnetism , zigzag , crystallography , cluster (spacecraft) , chain (unit) , ion , polyoxometalate , materials science , cage , stereochemistry , chemistry , condensed matter physics , physics , organic chemistry , catalysis , computer science , combinatorics , mathematics , geometry , astronomy , programming language
Not guilty—the cluster was framed! We report the proof of principle for an approach toward a novel type of inorganic–organic hybrid compound. Compound [Mn 2 {(OOCC 2 H 4 Ge) 4 S 6 }(MeOH)(dmf) 2 ] is constructed by inorganic cages (Ge 4 S 6 ) that are linked through terminal COO − donor groups by Mn 2+ ions within zigzag chains of corner‐sharing [MnO 6 ] units, exhibiting intrachain antiferromagnetic coupling (see figure).