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Construction of Polysubstituted Olefins through Ni‐Catalyzed Direct Activation of Alkenyl CO of Substituted Alkenyl Acetates
Author(s) -
Sun ChangLiang,
Wang Yang,
Zhou Xiao,
Wu ZhenHua,
Li BiJie,
Guan BingTao,
Shi ZhangJie
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200902785
Subject(s) - aryl , styrene , catalysis , chemistry , scheme (mathematics) , organic chemistry , construct (python library) , computer science , combinatorial chemistry , mathematics , programming language , mathematical analysis , alkyl , copolymer , polymer
Reliable companion : For the first time cross‐coupling between alkenyl acetates and arylboroxines/PhZnCl has been developed via Ni catalysis. Alkenyl acetates could be well‐differentiated from aryl acetates (see scheme). This reliable method provides a convenient pathway to construct polysubstituted styrene derivatives.