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Phosphorus Complexes of the First Expanded Isophlorins
Author(s) -
Miura Takahiro,
Higashino Tomohiro,
Saito Shohei,
Osuka Atsuhiro
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200902708
Subject(s) - phosphorus , amine gas treating , content (measure theory) , information retrieval , computer science , redox , chemistry , library science , combinatorial chemistry , organic chemistry , mathematics , mathematical analysis
Bisphosphorus complexes : Phosphorus complexes of octaphyrin were prepared upon the treatment of [36]octaphyrin(1.1.1.1.1.1.1.1) with PCl 3 in the presence of amine and a small amount of water (see figure). Reversible redox interconversions between 38π‐ and 40π‐electronic states were demonstrated.