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Ionic and Organometallic Reductions with N‐Heterocyclic Carbene Boranes
Author(s) -
Chu Qianli,
Makhlouf Brahmi Malika,
Solovyev Andrey,
Ueng ShauHua,
Curran Dennis P.,
Malacria Max,
Fensterbank Louis,
Lacôte Emmanuel
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200902450
Subject(s) - carbene , boranes , chemistry , borane , borohydride , catalysis , ionic bonding , organometallic chemistry , medicinal chemistry , boron , ionic liquid , molecule , organic chemistry , combinatorial chemistry , ion
Surgical reduction : N‐Heterocyclic carbene–borane complexes such as depicted are neutral, organic soluble analogues of borohydride anions with a weak hydridic character, compatible with organometallic catalysis. They are applicable for surgical reductions in complex, multifunctional molecules.