Synthesis and Reactivity of a Silylalkyl Double Tuck‐in Uranium Metallocene [(η 5 :η 1 ‐C 5 Me 4 SiMe 2 CH 2 ) 2 U] and its Conversion to Bis(tethered) Metallocenes | Zendy

Evans William J. | Zendy; Siladke Nathan A. | Zendy; Ziller Joseph W. | Zendy

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Synthesis and Reactivity of a Silylalkyl Double Tuck‐in Uranium Metallocene [(η 5 :η 1 ‐C 5 Me 4 SiMe 2 CH 2 ) 2 U] and its Conversion to Bis(tethered) Metallocenes

Author(s) -

Evans William J.,

Siladke Nathan A.,

Ziller Joseph W.

Publication year - 2010

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200902428

Subject(s) - reactivity (psychology) , metallocene , uranium , double bond , metallacycle , isocyanide , chemistry , crystallography , materials science , x ray crystallography , stereochemistry , polymer chemistry , physics , organic chemistry , metallurgy , polymerization , alternative medicine , pathology , polymer , medicine , diffraction , optics

Tuck in! CH bond activation involving two methyl groups in [(C 5 Me 4 SiMe 3 ) 2 UMe 2 ] generates a double tuck‐in uranium metallocene that allows UC bond reactivity to be studied in a tethered environment as shown here with isocyanide to make a bis(tethered iminoacyl) complex (see scheme).

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