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A 3D Copper(II) Coordination Framework Showing Different Kinetic and Thermodynamic Crystal Transformations through Removal of Guest Water Cubes
Author(s) -
Chen XuDong,
Zhao XiaoHu,
Chen Min,
Du Miao
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200902306
Subject(s) - dual (grammatical number) , supramolecular chemistry , copper , scheme (mathematics) , single crystal , kinetic energy , crystallography , coordination number , computer science , coordination complex , crystal (programming language) , crystal structure , chemistry , materials science , physics , mathematics , organic chemistry , metal , philosophy , ion , mathematical analysis , linguistics , programming language , quantum mechanics
Dual nature : A 3D Cu II coordination framework 1 ⋅2 H 2 O shows distinct single‐crystal to single‐crystal transformations by removing guest cubic water clusters under different conditions, forming a pair of supramolecular isomers with a 3D lvt (threefold interpenetrating) or 2D kgm (Kagomé) network, which also reveals both rigid and flexible nature of this dual crystalline material (see scheme).