Pentacene‐Based Polycyclic Aromatic Hydrocarbon Dyads with Cofacial Solid‐State π‐Stacking | Zendy

Lehnherr Dan | Zendy; Murray Adrian H. | Zendy; McDonald Robert | Zendy; Ferguson Michael J. | Zendy; Tykwinski Rik R. | Zendy

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Pentacene‐Based Polycyclic Aromatic Hydrocarbon Dyads with Cofacial Solid‐State π‐Stacking

Author(s) -

Lehnherr Dan,

Murray Adrian H.,

McDonald Robert,

Ferguson Michael J.,

Tykwinski Rik R.

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200902179

Subject(s) - pentacene , stacking , chromophore , polycyclic aromatic hydrocarbon , phenanthrene , photochemistry , cyclic voltammetry , molecule , absorption spectroscopy , aromaticity , solid state , aromatic hydrocarbon , hydrocarbon , chemistry , materials science , electrode , organic chemistry , electrochemistry , physics , quantum mechanics , thin film transistor

Give me five! Pentacene‐based polycyclic aromatic hydrocarbon (PAH) dyads are synthesized via an unsymmetrical pentacene building block. These molecules exhibit cofacial solid‐state π‐stacking as a result of the large aromatic chromophores. The choice of the PAH attached to the pentacene (see picture) influences the electronic properties as determined by UV/Vis absorption/emission spectroscopy and cyclic voltammetry.

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