The Subtle Influence of Binary versus Homoatomic Zintl Ions: The Phenyl‐Ligated Trimetallic Cage [Sn 2 Sb 5 (ZnPh) 2 ] 3− | Zendy

Lips Felicitas | Zendy; Schellenberg Inga | Zendy; Pöttgen Rainer | Zendy; Dehnen Stefanie | Zendy

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The Subtle Influence of Binary versus Homoatomic Zintl Ions: The Phenyl‐Ligated Trimetallic Cage [Sn 2 Sb 5 (ZnPh) 2 ] 3−

Author(s) -

Lips Felicitas,

Schellenberg Inga,

Pöttgen Rainer,

Dehnen Stefanie

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200902163

Subject(s) - crypt , ethylenediamine , binary number , liquid ammonia , crystallography , content (measure theory) , ion , chemistry , ammonia , stereochemistry , computer science , mathematics , inorganic chemistry , organic chemistry , arithmetic , mathematical analysis , computer security

Zintlating stuff! The first binary Sn/Sb Zintl anions produced by solution techniques were obtained in [K([2.2.2]crypt)] 2 [Sn 2 Sb 2 ] ⋅ en (en=ethylenediamine) and [K 6 (NH 3 ) 9 ][Sn 3 Sb 4 ] upon extraction of K 8 SnSb 4 by en or liquid ammonia. Addition of ZnPh 2 to the en/[2.2.2]crypt extract resulted in the formation of a heterotrimetallic complex in [K([2.2.2]crypt)] 3 [Sn 2 Sb 5 (ZnPh) 2 ] ⋅ en ⋅ 0.5tol (see scheme).

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