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An Interpenetrated Framework Material with Hysteretic CO 2 Uptake
Author(s) -
Mulfort Karen L.,
Farha Omar K.,
Malliakas Christos D.,
Kanatzidis Mercouri G.,
Hupp Joseph T.
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200902104
Subject(s) - hysteresis , sorption , powder diffraction , metal organic framework , adsorption , materials science , desorption , crystallography , diffraction , chemical engineering , chemistry , organic chemistry , condensed matter physics , physics , optics , engineering
Abstract A new, twofold interpenetrated metal–organic framework (MOF) material has been synthesized that demonstrates dramatic steps in the adsorption and hysteresis in the desorption of CO 2 . Measurement of the structure by powder X‐ray diffraction (PXRD) and pair distribution function (PDF) analysis indicates that structural changes upon CO 2 sorption most likely involve the interpenetrated frameworks moving with respect to each other.