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New Arylaziridinyldifluoroborates: Useful Suzuki–Miyaura Reagents
Author(s) -
Luisi Renzo,
Giovine Arianna,
Florio Saverio
Publication year - 2010
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200902056
Subject(s) - reagent , bifunctional , chemistry , combinatorial chemistry , class (philosophy) , computer science , catalysis , organic chemistry , artificial intelligence
Blossoming promises fruit ! A new class of shelf stable organoboron reagents has been obtained from ortho ‐ and laterally lithiated aziridines and benzylamines. Their usefulness as Suzuki–Miyaura reagents has been investigated, proving that they could be fruitful reagents for the preparation of arylated aziridines and benzylamines, even in enantioenriched form, and promising new bifunctional Lewis pairs for catalysis or small‐molecule binding.