Synthesis of a Thorium Tuck‐In Complex, [(η 5 :η 1 ‐C 5 Me 4 CH 2 )(η 5 ‐C 5 Me 5 )Th{ i PrNC(Me)N i Pr}], by CH Bond Activation Initiated by (C 5 Me 5 ) − | Zendy

Evans William J. | Zendy; Walensky Justin R. | Zendy; Ziller Joseph W. | Zendy

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Synthesis of a Thorium Tuck‐In Complex, [(η 5 :η 1 ‐C 5 Me 4 CH 2 )(η 5 ‐C 5 Me 5 )Th{ i PrNC(Me)N i Pr}], by CH Bond Activation Initiated by (C 5 Me 5 ) −

Author(s) -

Evans William J.,

Walensky Justin R.,

Ziller Joseph W.

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200901942

Subject(s) - thorium , cationic polymerization , chemistry , ligand (biochemistry) , group 2 organometallic chemistry , metallocene , radiochemistry , crystallography , stereochemistry , physics , nuclear physics , molecule , polymer chemistry , organic chemistry , uranium , biochemistry , receptor , polymerization , polymer

Tuck in! (C 5 Me 5 ) − effects alkyl CH bond activation (Th) and reduction (U) with the cationic complexes [(C 5 Me 5 ) 2 An{ i PrNC(Me)N i Pr}][BPh 3 Me] to form the first structurally characterized thorium complex that contains a tuck‐in metalated (C 5 Me 5 CH 2 ) 2− ligand (see figure) and a trivalent metallocene amidinate [(C 5 Me 5 ) 2 U{ i PrNC(Me)N i Pr}].

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