Trapping Reactive Metal–Carbene Complexes by a Bis‐Pocket Porphyrin: X‐ray Crystal Structures of RuCHCO 2 Et and  trans ‐[Ru(CHR)(CO)] Species and Highly Selective Carbenoid Transfer Reactions | Zendy

Deng QingHai | Zendy; Chen Jian | Zendy; Huang JieSheng | Zendy; Chui Stephen SinYin | Zendy; Zhu Nianyong | Zendy; Li GuangYu | Zendy; Che ChiMing | Zendy

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Trapping Reactive Metal–Carbene Complexes by a Bis‐Pocket Porphyrin: X‐ray Crystal Structures of RuCHCO 2 Et and trans ‐[Ru(CHR)(CO)] Species and Highly Selective Carbenoid Transfer Reactions

Author(s) -

Deng QingHai,

Chen Jian,

Huang JieSheng,

Chui Stephen SinYin,

Zhu Nianyong,

Li GuangYu,

Che ChiMing

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200901895

Subject(s) - porphyrin , carbene , chemoselectivity , steric effects , ligand (biochemistry) , aryl , ethyl diazoacetate , x ray , ruthenium , chemistry , crystal (programming language) , stereochemistry , catalysis , photochemistry , organic chemistry , physics , computer science , alkyl , biochemistry , receptor , quantum mechanics , cyclopropanation , programming language

What's in my pockets? By employing Suslick's bis‐pocket porphyrin (ttppp), a reactive MCHCO 2 Et complex and a trans ‐[M(CHR)(CO)] (M=Ru) complex have been structurally characterized by X‐ray crystal analysis. The sterically encumbered ttppp ligand has a significant impact on both the diastereoselectivity and chemoselectivity in metalloporphyrin‐catalyzed reactions of ethyl diazoacetate with conjugated aryl dienes.

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