Specific Interaction between Chloroform and the Pockets of Triangular Annulene Derivatives Providing Symmetry Carry‐Over Crystallization | Zendy

Hisaki Ichiro | Zendy; Senga Hirofumi | Zendy; Sakamoto Yuu | Zendy; Tsuzuki Seiji | Zendy; Tohnai Norimitsu | Zendy; Miyata Mikiji | Zendy

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Specific Interaction between Chloroform and the Pockets of Triangular Annulene Derivatives Providing Symmetry Carry‐Over Crystallization

Author(s) -

Hisaki Ichiro,

Senga Hirofumi,

Sakamoto Yuu,

Tsuzuki Seiji,

Tohnai Norimitsu,

Miyata Mikiji

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200901848

Subject(s) - annulene , chloroform , crystallization , symmetry (geometry) , chemistry , molecule , crystallography , computational chemistry , chemical physics , stereochemistry , organic chemistry , geometry , mathematics

What's it got in its pockets? Symmetry carry‐over crystallization of hexadehydrotribenzo[12]annulene derivatives was provided by specific complexation between the annulene and the chloroform molecule through mainly dispersion forces (see picture). In the complex, a hydrogen atom of the chloroform fits into the annulene's “pocket” surrounded by π electrons.

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