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A Coordination Controlled Aryl–Halide Oxidative Addition to Platinum
Author(s) -
Zenkina Olena V.,
Karton Amir,
Shimon Linda J. W.,
Martin Jan M. L.,
van der Boom Milko E.
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200901781
Subject(s) - halide , aryl , platinum , coordination complex , reactivity (psychology) , aryl halide , oxidative addition , chemistry , substrate (aquarium) , combinatorial chemistry , metal , medicinal chemistry , organic chemistry , catalysis , medicine , alkyl , alternative medicine , oceanography , pathology , geology
Mission control : η 2 ‐Coordination of zero‐valent platinum is followed by metal insertion into a carbonhalide bond of a stilbene‐based substrate. The overall reactivity trend is opposite from those of other aryl halides and is controlled by the coordination chemistry.