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Gold Catalysis: Enantiotopos Selection
Author(s) -
Hashmi A. Stephen K.,
Hamzić Melissa,
Rominger Frank,
Bats Jan W.
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200901695
Subject(s) - cycloisomerization , cationic polymerization , furan , selection (genetic algorithm) , scheme (mathematics) , computer science , substrate (aquarium) , catalysis , chemistry , combinatorial chemistry , organic chemistry , biology , mathematics , artificial intelligence , ecology , mathematical analysis
Selecting one out of two enantiotopic alkynes : A furan–diyne substrate with enantiotopic alkynyl groups was prepared and the gold‐catalyzed cycloisomerization by a series of different chiral cationic gold(I) complexes was investigated (see scheme).