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Variations in the Mechanisms of Direct Metallation of Cyclic and Acyclic Aminals
Author(s) -
Kamps Ina,
Bojer Daniel,
Hayes Stuart A.,
Berger Raphael J. F.,
Neumann Beate,
Mitzel Norbert W.
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200901570
Subject(s) - computer science
Different regioselectivity is observed for the lithiation reactions of open‐chain and ring‐type aminals; the reasons for this are attributed to the restriction of movements of groups by the ring structures.