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A Dy 10 Cluster Incorporates Two Sets of Vertex‐Sharing Dy 3 Triangles
Author(s) -
Ke Hongshan,
Xu GongFeng,
Zhao Lang,
Tang Jinkui,
Zhang XiYan,
Zhang HongJie
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200901506
Subject(s) - cluster (spacecraft) , deprotonation , lanthanide , vertex (graph theory) , denticity , crystallography , combinatorics , fusion , ligand (biochemistry) , chemistry , mathematics , materials science , computer science , crystal structure , ion , computer network , graph , linguistics , philosophy , receptor , biochemistry , organic chemistry
A fusion of polygons : A unique Dy 10 cluster with four fused Dy 3 triangles has been synthesized by incorporating the polydentate Schiff base ligand H 4 L in two different binding modes in its mono‐ and di‐deprotonated state (see figure). This Dy 10 compound represents the largest lanthanide cluster based on the peculiar Dy 3 triangles, therefore opening a promising route toward the design of novel magnetic materials.
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