Premium
Metal–Organic‐Framework‐Based Catalyst for Highly Efficient H 2 Generation from Aqueous NH 3 BH 3 Solution
Author(s) -
Li Yaoqi,
Xie Lei,
Li Yan,
Zheng Jie,
Li Xingguo
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200901465
Subject(s) - catalysis , aqueous solution , metal organic framework , metal , hydrogen , chemistry , computer science , chemical engineering , database , organic chemistry , engineering , adsorption
Hydrogen release : A novel catalyst based on a MOF (metal–organic framework, see figure) exhibits unexpectedly high catalytic activity for hydrogen generation from aqueous NH 3 BH 3 solution. The H 2 release was complete within 5 min (NH 3 BH 3 , 0.32 m ) at 298 K in air. This work presents a new strategy for a highly efficient catalyst preparation based on MOF‐stabilised metal clusters.
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom