Catalytic Organocopper Chemistry from Organosiloxane Reagents | Zendy

Herron Jessica R. | Zendy; Russo Vincenzo | Zendy; Valente Edward J. | Zendy; Ball Zachary T. | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Catalytic Organocopper Chemistry from Organosiloxane Reagents

Author(s) -

Herron Jessica R.,

Russo Vincenzo,

Valente Edward J.,

Ball Zachary T.

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200901438

Subject(s) - silane , reagent , catalysis , reactivity (psychology) , chemistry , stoichiometry , fluoride , ligand (biochemistry) , combinatorial chemistry , copper , computer science , organic chemistry , inorganic chemistry , medicine , biochemistry , alternative medicine , receptor , pathology

Organosilanes serve as precursors to organocopper intermediates in a copper‐catalyzed addition to vinylepoxides (see scheme). Ligand structure has a significant effect on the reactivity of the organocopper intermediate, and the catalysis proceeds without the need for a stoichiometric silane activator such as fluoride.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research