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Oxidative Addition Reactions of Element–Hydrogen Bonds with Different Polarities to a Gallium(I) Compound
Author(s) -
Seifert Annekathrin,
Scheid Dominik,
Linti Gerald,
Zessin Thomas
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200901403
Subject(s) - diethylamine , oxidative addition , chemistry , gallium , hydrogen bond , derivative (finance) , mass spectrometry , hydride , spectroscopy , crystal structure , medicinal chemistry , hydrogen , nuclear magnetic resonance spectroscopy , crystallography , photochemistry , molecule , stereochemistry , organic chemistry , catalysis , physics , quantum mechanics , financial economics , economics , chromatography
The gallium(I) derivative [Ga({N(dipp)CMe} 2 CH)] ( 1 ; dipp=2,6‐diisopropylphenyl) undergoes facile oxidative addition reactions with various element–hydrogen bonds including NH, PH, OH, SnH, and HH bonds. This was demonstrated by its reaction with triphenyltin hydride, ethanol, water, diethylamine, diphenylphosphane, and dihydrogen. All products were characterized by means of single‐crystal X‐ray structure determination, NMR spectroscopy, IR spectroscopy, and mass spectrometry.