Divalent E(0) Compounds (E=Si–Sn)

Quantum‐chemical calculations at the BP86/TZVPP level of theory have been carried out for compounds EL 2 for E=Si, Ge, Sn, where L is a five‐membered cyclic ylidene or N ‐heterocyclic ylidene. The theoretical results provide evidence for the classification of the complexes as divalent E(0) compounds, where the bonding situation is best described in terms of donor–acceptor interactions between a bare atom E, which retains its valence electrons as two lone pairs, and two donor ligands L→E←L. The molecules are very strong donors, which may bind one or two Lewis acids. Divalent E(0) compounds have unusually high second proton affinities and they are strong σ donor ligands. The calculations predict that complexes of EL 2 with one or two BH 3 ligands are stable enough to become isolated in a condensed phase. It is also shown that the bond dissociation energies (BDEs) of transition‐metal complexes [(CO) 5 WD] and [(CO) 3 NiD], where D=EL 2 are rather high. The BDE of some ligands D are higher than those of CO in the metal carbonyls.