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Self‐Assembled Monolayers of Mono‐Tetrathiafulvalene Calix[4]pyrroles and Their Electrochemical Sensing of Chloride
Author(s) -
Jensen Lise G.,
Nielsen Kent A.,
Breton Tony,
Sessler Jonathan L.,
Jeppesen Jan O.,
Levillain Eric,
Sanguinet Lionel
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200901394
Subject(s) - tetrathiafulvalene , monolayer , electrochemistry , chloride , self assembled monolayer , materials science , chemistry , inorganic chemistry , organic chemistry , nanotechnology , molecule , electrode
Chloride anion sensing : Immobilization of a calix[4]pyrrole endowed with a redox‐active mono‐tetrathiafulvalene unit on a gold surface produces a redox‐responsive self‐assembled monolayer that allows for the electrochemical detection of chloride anions down to the submicromolar level (see figure).