Oxygen‐Atom Transfer by a Naked Manganese(V)–Oxo–Porphyrin Complex Reveals Axial Ligand Effect | Zendy

Crestoni Maria Elisa | Zendy; Fornarini Simonetta | Zendy; Lanucara Francesco | Zendy

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Oxygen‐Atom Transfer by a Naked Manganese(V)–Oxo–Porphyrin Complex Reveals Axial Ligand Effect

Author(s) -

Crestoni Maria Elisa,

Fornarini Simonetta,

Lanucara Francesco

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200901361

Subject(s) - porphyrin , manganese , reactivity (psychology) , ligand (biochemistry) , chemistry , photochemistry , oxygen , organic chemistry , receptor , pathology , medicine , biochemistry , alternative medicine

The reactivity of naked oxygenating intermediates is proven! The ultimate high‐valent manganese(V)–porphyrin complex, devoid of any additional trans ligand, is produced as a naked, gaseous species. An insight into its inherent reactivity is obtained providing definitive evidence of pronounced epoxidation activity. In contrast, the trans ‐dioxo–Mn V –porphyrin is remarkably inert.

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