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Regioselective Ru‐Catalyzed Direct 2,5,8,11‐Alkylation of Perylene Bisimides
Author(s) -
Nakazono Satomi,
Imazaki Yusuke,
Yoo Hyejin,
Yang Jaesung,
Sasamori Takahiro,
Tokitoh Norihiro,
Cédric Tassel,
Kageyama Hiroshi,
Kim Dongho,
Shinokubo Hiroshi,
Osuka Atsuhiro
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200901318
Subject(s) - regioselectivity , perylene , alkylation , ruthenium , catalysis , chemistry , combinatorial chemistry , computer science , organic chemistry , molecule
Regioselective direct alkylation of perylene bisimides at 2,5,8,11‐positions has been achieved by reaction with terminal alkenes under ruthenium catalysis by the Murai–Chatani–Kakiuchi protocol (see scheme). Alkylation of perylene bisimides results in enhanced solubility and quantum efficiency in the solid state.