Stabilisation of a Highly Reactive Bis(μ‐oxo)dicopper(III) Species at Room Temperature by Electronic and Steric Constraint of an Unconventional Nitrogen Donor Ligand | Zendy

HerresPawlis Sonja | Zendy; Binder Stephan | Zendy; Eich Andreas | Zendy; Haase Roxana | Zendy; Schulz Benjamin | Zendy; Wellenreuther Gerd | Zendy; Henkel Gerald | Zendy; Rübhausen Michael | Zendy; MeyerKlaucke Wolfram | Zendy

Premium

Stabilisation of a Highly Reactive Bis(μ‐oxo)dicopper(III) Species at Room Temperature by Electronic and Steric Constraint of an Unconventional Nitrogen Donor Ligand

Author(s) -

HerresPawlis Sonja,

Binder Stephan,

Eich Andreas,

Haase Roxana,

Schulz Benjamin,

Wellenreuther Gerd,

Henkel Gerald,

Rübhausen Michael,

MeyerKlaucke Wolfram

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200901092

Subject(s) - steric effects , ligand (biochemistry) , chemistry , raman spectroscopy , guanidine , diamine , constraint (computer aided design) , ground state , excited state , nitrogen , spectroscopy , photochemistry , stereochemistry , polymer chemistry , organic chemistry , physics , atomic physics , mathematics , optics , biochemistry , receptor , geometry , quantum mechanics

Amazingly stable : The bis(guanidine) ligand N 1 , N 3 ‐bis[bis(2,2,6,6‐tetramethylpiperidin‐1‐yl)methylen]propan‐1,3‐diamine stabilizes the first bis(μ‐oxo)dicopper(III) complex (see figure) at room temperature. This complex is characterized in the ground state and in the optical excited state by a combination of EXAFS and resonance Raman spectroscopy.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research