Facile Cyclometalation Reactions of Cp–Zirconium Complexes with Weakly Lewis Acidic Pendent Boron Functionalities | Zendy

Emmert Marion | Zendy; Kehr Gerald | Zendy; Fröhlich Roland | Zendy; Erker Gerhard | Zendy

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Facile Cyclometalation Reactions of Cp–Zirconium Complexes with Weakly Lewis Acidic Pendent Boron Functionalities

Author(s) -

Emmert Marion,

Kehr Gerald,

Fröhlich Roland,

Erker Gerhard

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200900981

Subject(s) - bifunctional , reactivity (psychology) , hydroboration , zirconium , intramolecular force , lewis acids and bases , chemistry , borane , metallocene , boron , combinatorial chemistry , organic chemistry , polymerization , polymer , catalysis , medicine , alternative medicine , pathology

Intramolecular hydroboration : Representative examples of Group 4 metallocene methyl complexes, including their synthesis, structure, and reactivity are discussed. The figure shows the thermolysis of the tethered bifunctional Zr/B compound 1 , which results in the formation of “tucked‐in” complex 2 with loss of MeBBN.

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