Efficient Reoxidation of Palladium by a Hybrid Catalyst in Aerobic Palladium‐Catalyzed Carbocyclization of Enallenes | Zendy

Johnston Eric V. | Zendy; Karlsson Erik A. | Zendy; Lindberg Staffan A. | Zendy; Åkermark Björn | Zendy; Bäckvall JanE. | Zendy

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Efficient Reoxidation of Palladium by a Hybrid Catalyst in Aerobic Palladium‐Catalyzed Carbocyclization of Enallenes

Author(s) -

Johnston Eric V.,

Karlsson Erik A.,

Lindberg Staffan A.,

Åkermark Björn,

Bäckvall JanE.

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200900980

Subject(s) - palladium , catalysis , yield (engineering) , molecular oxygen , chemistry , electron transfer , scheme (mathematics) , computer science , combinatorial chemistry , photochemistry , organic chemistry , materials science , mathematics , metallurgy , mathematical analysis

Reoxidation : Smooth palladium‐catalyzed aerobic CC bond formation takes place in essentially quantitative yield with a hybrid catalyst (see scheme, E=CO 2 Me, R=R′=Me or R,R′=(CH 2 ) 5 ) through facilitated electron transfer from reduced palladium to molecular oxygen.

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