A New and Flexible Synthesis of 4‐Hydroxypyridines: Rapid Access to Caerulomycins A, E and Functionalized Terpyridines | Zendy

Dash Jyotirmayee | Zendy; Reissig HansUlrich | Zendy

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A New and Flexible Synthesis of 4‐Hydroxypyridines: Rapid Access to Caerulomycins A, E and Functionalized Terpyridines

Author(s) -

Dash Jyotirmayee,

Reissig HansUlrich

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200900939

Subject(s) - scheme (mathematics) , simple (philosophy) , computer science , combinatorial chemistry , chemistry , database , mathematics , philosophy , mathematical analysis , epistemology

Simple, but yet unknown : 1,3‐Diketones, ammonia, and carboxylic acids are the precursors for the efficient synthesis of 4‐hydroxypyridines and the corresponding nonaflate derivatives. This provides simple and practical access to a variety of highly substituted pyridine derivatives, including antibiotic natural products such as caerulomycins A, E and functionalized terpyridines (see scheme).

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