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1,2,4‐Diazaphospholide Complexes of Tin(II): From Nitride Stannylene to Stannylenated Ammonium Ions
Author(s) -
Pi Chengfu,
Elguero José,
Wan Li,
Alkorta Ibon,
Zheng Wenjun,
Weng Linhong,
Chen Zhenxia,
Wu Limin
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200900867
Subject(s) - tin , counterion , ammonium , divalent , chemistry , ion , onium , amine gas treating , inorganic chemistry , samarium , nitride , derivative (finance) , tris , ligand (biochemistry) , organic chemistry , receptor , biochemistry , layer (electronics) , financial economics , economics
Tin knows its oniums! An unusual nitride tetrastannylene and a stannylenated ammonium ion stabilized by a samarium tetradiazaphospholido counterion are the first examples of a tris(organostannylenyl)amine derivative and a divalent tin coordinate onium ion that incorporates 1,2,4‐diazaphospholide ligand (see figure).