Re 4 Si 7 , First in a New MoSi 2 ‐Based Family of 14‐Electron Phases | Zendy

Fredrickson Daniel C. | Zendy; Boström Magnus | Zendy; Grin Yuri | Zendy; Lidin Sven | Zendy

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Re 4 Si 7 , First in a New MoSi 2 ‐Based Family of 14‐Electron Phases

Author(s) -

Fredrickson Daniel C.,

Boström Magnus,

Grin Yuri,

Lidin Sven

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200900739

Subject(s) - electron , electronic structure , cluster analysis , condensed matter physics , crystallography , physics , materials science , computer science , chemistry , quantum mechanics , machine learning

Magic number 14! Re 4 Si 7 is the first complex structure outside of the Nowotny Chimney Ladder series recognized as adhering to the 14‐electron rule. Its structure is based on Si vacancies in the MoSi 2 structure pattern clustering into periodic edge‐dislocations (see figure). Coincident with its 14‐electron count is a pseudo‐gap in its electronic density of states.

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