Guest Binding Drives Reversible Atropisomerism in Cavitand Hosts | Zendy

Nguyen Thanh V. | Zendy; Sinclair David J. | Zendy; Willis Anthony C. | Zendy; Sherburn Michael S. | Zendy

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Guest Binding Drives Reversible Atropisomerism in Cavitand Hosts

Author(s) -

Nguyen Thanh V.,

Sinclair David J.,

Willis Anthony C.,

Sherburn Michael S.

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200900695

Subject(s) - cavitand , atropisomer , substituent , affinities , chemistry , solvent polarity , solvent , binding affinities , stereochemistry , crystallography , organic chemistry , receptor , crystal structure , biochemistry , supramolecular chemistry

Guest‐love‐ometer : The equilibrium inside – outside atropisomeric ratio of ortho ‐substituted phenyl cavitands shows a strong solvent dependence. The competition between the ortho ‐substituent and the solvent guest for the bowl cavity leads to a sensitive system for the measurement of relative guest binding affinities.

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