Helical Chiral Pyridine  N ‐Oxides: A New Family of Asymmetric Catalysts | Zendy

Chen Jinshui | Zendy; Takenaka Norito | Zendy

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Helical Chiral Pyridine N ‐Oxides: A New Family of Asymmetric Catalysts

Author(s) -

Chen Jinshui,

Takenaka Norito

Publication year - 2009

Publication title -

chemistry – a european journal

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.687

H-Index - 242

eISSN - 1521-3765

pISSN - 0947-6539

DOI - 10.1002/chem.200900607

Subject(s) - enantioselective synthesis , pyridine , optically active , catalysis , nucleophile , chemistry , combinatorial chemistry , alkyl , pyridine n oxide , ring (chemistry) , epoxide , organic chemistry

Optically active chiral alkyl chlorides are valuable compounds because of their bioactivity and versatile synthetic utility. Accordingly, the ring opening of epoxides with a chloride nucleophile stands as an important goal in asymmetric catalysis. We describe herein recent advances in the design and development of chiral pyridine N ‐oxide catalysts for the enantioselective synthesis of chlorohydrins.

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