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Periodic Mesoporous Organosilica Materials: Self‐Assembly of Carbamothioic Acid‐Bridged Organosilane Precursors
Author(s) -
Gao Ling,
Wei Feng,
Zhou Yu,
Fan Xiao Xing,
Wang Ying,
Zhu Jian Hua
Publication year - 2009
Publication title -
chemistry – a european journal
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.687
H-Index - 242
eISSN - 1521-3765
pISSN - 0947-6539
DOI - 10.1002/chem.200900352
Subject(s) - tetraethyl orthosilicate , mesoporous organosilica , mesoporous material , materials science , chemical engineering , orthosilicate , hydrothermal circulation , hybrid material , pulmonary surfactant , poloxamer , hydrothermal synthesis , silsesquioxane , catalysis , organic chemistry , inorganic chemistry , nanotechnology , chemistry , mesoporous silica , copolymer , composite material , polymer , engineering
A new series of carbamothioic acid‐containing periodic mesoporous organosilica (PMO) materials has been synthesized by a direct cocondensation method, in which an organosilica precursor N , S ‐bis[3‐(triethoxysilyl)propyl]carbamothioic acid (MI) is treated with tetraethyl orthosilicate (TEOS), and the nonionic surfactant Pluronic 123 (P123) is used as a template under acidic conditions in the presence of inorganic additives. Moreover, the synthesis of the PMO material consisting of the MI precursor without TEOS has been realized. These novel PMO materials have large surface areas, well‐ordered mesoporous structures, hollow fiberlike morphologies, and thick walls. They are also structurally well‐ordered with a high organosilica precursor content, and the carbamothioic acid groups are thermally stable up to 250 °C. Furthermore, the organosilica materials exhibit hydrothermal stability in basic solution.